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东亚区域对流层臭氧及其前体物的季节性关联

刘宁微 马建中

刘宁微, 马建中. 东亚区域对流层臭氧及其前体物的季节性关联. 应用气象学报, 2017, 28(4): 427-435. DOI: 10.11898/1001-7313.20170404..
引用本文: 刘宁微, 马建中. 东亚区域对流层臭氧及其前体物的季节性关联. 应用气象学报, 2017, 28(4): 427-435. DOI: 10.11898/1001-7313.20170404.
Liu Ningwei, Ma Jianzhong. Seasonal relationships between tropospheric ozone and its precursors over East Asia. J Appl Meteor Sci, 2017, 28(4): 427-435. DOI:  10.11898/1001-7313.20170404.
Citation: Liu Ningwei, Ma Jianzhong. Seasonal relationships between tropospheric ozone and its precursors over East Asia. J Appl Meteor Sci, 2017, 28(4): 427-435. DOI:  10.11898/1001-7313.20170404.

东亚区域对流层臭氧及其前体物的季节性关联

DOI: 10.11898/1001-7313.20170404
资助项目: 

国家自然科学基金项目 91537107

中国气象局沈阳大气环境研究所基本科研业务经费项目 2015IAE-CMA06

详细信息
    通信作者:

    马建中, email:mjz@camscma.cn

Seasonal Relationships Between Tropospheric Ozone and Its Precursors over East Asia

  • 摘要: 利用2010—2012年对流层臭氧(O3)及其多种前体物的卫星遥感资料和全球水汽再分析资料,研究东亚区域O3及其前体物的时空分布,以及在中国东部(分为南、北两部分)相关性的季节变化。结果表明:东亚区域NO2与CO的对流层柱含量均表现为冬季高、夏季低的时空变化形式。O3对流层柱含量夏季达到峰值,冬季为谷值。中国东部的北部与南部地区O3与NO2均在夏秋季呈正相关,冬春季呈负相关。夏季大部分地区NOx的光化学循环反应对O3生成有积极的促进作用,冬季大部分地区O3的光化学循环生成受到抑制。O3与CO在北部地区夏秋季和南部地区夏季正相关性最大,无论是在北部还是南部地区,O3与CO的相关性在轻污染情况下最大,而在重污染和背景情况下较小,表明重污染气团向下风方的输送更有利于O3的光化学生成。O3与水汽在北部和南部地区的多数时间均呈较显著的正相关性,而在南部地区夏季和北部地区冬季具有较大的负相关性,反映出不同的环流形式、气团来源及伴随的天气条件变化对O3分布的影响。
  • 图  1  东亚区域对流层NO2柱含量的季节分布

    (a)春季, (b)夏季, (c)秋季, (d)冬季

    Fig. 1  Seasonal variations of tropospheric NO2 column densities over East Asia

    (a)spring, (b)summer, (c)autumn, (d)winter

    图  2  东亚区域对流层CO柱含量的季节分布

    (a)春季, (b)夏季, (c)秋季, (d)冬季

    Fig. 2  Seasonal variations of tropospheric CO column densities over East Asia

    (a)spring, (b)summer, (c)autumn, (d)winter

    图  3  东亚区域对流层O3柱含量的季节分布

    (a)春季,(b)夏季,(c)秋季,(d)冬季

    Fig. 3  Seasonal variations of tropospheric ozone column densities over East Asia

    (a)spring, (b)summer, (c)autumn, (d)winter

    图  4  北部地区各季节不同NO2阈值下O3与CO的散点图

    (a)春季,(b)夏季,(c)秋季,(d)冬季

    Fig. 4  Scattering plots between ozone and CO based on different NO2 thresholds over the northern region in different seasons

    (a)spring, (b)summer, (c)autumn, (d)winter

    图  5  南部地区各季节不同NO2阈值下O3与CO的散点图

    (a)春季,(b)夏季,(c)秋季,(d)冬季

    Fig. 5  Scattering plots between ozone and CO based on different NO2 thresholds over the southern region in different seasons

    (a)spring, (b)summer, (c)autumn, (d)winter

    表  1  对流层O3分别与NO2,CO,水汽的线性相关系数

    Table  1  Correlation coefficients of ozone with NO2, CO and vapour

    区域季节O3与NO2O3与COO3与水汽
    北部
    (N=1953)
    -0.045*0.160**0.322**
    0.489**0.453**0.510**
    0.086**0.446**0.633**
    -0.245**-0.062**-0.356**
    南部
    (N=1449)
    -0.085**0.066*0.475**
    0.550**0.500**-0.318**
    0.052*0.216**0.226**
    -0.104**0.177**0.253**
    注:N为总样本量,*表示达到0.05显著性水平,**表示达到0.01显著性水平。
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  • 收稿日期:  2017-02-20
  • 修回日期:  2017-06-01
  • 刊出日期:  2017-07-31

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